The GEISA 2011 sub-database on Atmospheric Aerosols

Besides the molecular species which define the gaseous infrared opacity in the Earths atmosphere aerosol particles also contribute to this opacity. Consequently, a common GEISA and GEISA/IASI aerosols sub-database has been elaborated. It gathers data on complex refractive indices of selected basic aerosol components : Massie (1994, 2003), Hess et al. (1998), Koepke et al.(1997), Rublev (1994).

The various available aerosols compounds have been distributed among four classes:

Acids Ash – Soot – Carbonaceous Water – Ice Solids – Salts

Description of columns :

Column 1 : molecular species names
Column 2 : spectral coverage (cm-1)
Column 3 : overall temperature range (K)
Column 4 : Concentration range in % (9.99 when unknown or not applicable)
Column 5 : number of associated files
Column 6 : related references
Column 7 : related reference numbers

Reference names for file selection using associated search engine are in red

Acids
Component Spectral
coverage (cm-1)
Temperature
range (K)
Concentration
range (%)
Number
of files
References Ref No

Sulfuric Acid
H2SO4/H2O
2 – 16382 183-293 0-80 117 Biermann et al. (2000) [1]
825 – 4701 200 – 300 32-87 61 Niedziela et al. (1999) [14]
499 – 3648 215 45 – 80 16 Tisdale et al. (1998) [26]
200 – 50000 215-300 75 2 Hummel et al. (1988) [11]
250 – 40000 293 75 7 Fenn et al. (1985) [8]
250 – 40000 293 75 1 Shettle and Fenn (1979) [23]
400 – 27800 293 25-95 12 Palmer and Williams (1975) [17]
747 – 1571 293 75-90 2 Remsberg et al. (1974) [21]
250 – 40000 293 75 1 Volz et al. (1972a, 1972b, 1973);
Shettle and Fenn (1979).
[30, 31, 32]
[23]
Nitric Acid
HNO3/H2O
431 – 16382 213 – 293 0 -50 62 Biermann et al. (2000) [1]
754 – 4701 220 35 -70 10 Norman et al. (1999) [15]
250 – 4988 293 3 – 70 12 Querry and Tyler (1980) [19]
850 – 1088 293 38 1 Remsberg et al. (1974) [21]
Ternary
H2SO4/HNO3/H2O
825 – 5000 220 15-45 (HNO3)
10-40 (H2SO4)
12 Norman et al. (2002) [16]
Nitric Acid amorphous solutions hydrates (1) 482 – 7000 153 – 196 99 – 9.99 8 Toon et al. (1994)

Richwine et al. (1995)

[28]
[22]

(1) Nitric Acid amorphous solutions and Hydrates :
(one file for each component)
β NATNitric acid trihydrate solid film at 196 K
α NATNitric acid trihydrate solid film at 181 K
NAD-filmNitric acid dihydrate solid film at 184 K
NAM-filmNitric acid monohydrate solid film at 179 K
NATNitric acid trihydrate at 160 K
a NAD-filmAmorphous NAD solid solution film at 153 K
a NAM-filmAmorphous NAT solid solution film at 153 K
a NAT-filmAmorphous NAM solid solution film at153 K

Ash – Soot – Carbonaceous
Component Spectral
coverage (cm-1)
Temperature
range (K)
Concentration
range (%)
Number
of files
References Ref No
Volcanic Ash 250 – 50000 184 9.99 1 Volz (1972a);
Shettle and Fenn (1979)
[30, 32]
[23]
Soots 250 – 50000 293 9.99 1 Shettle and Fenn (1979) [23]
Carbonaceous 250 – 50000 293 9.99 1 Shettle and Fenn (1979)
Twitty and Weinman (1971) ;
[23]
[29]

Water – Ice
Component Spectral
coverage (cm-1)
Temperature
range (K)
Concentration
range (%)
Number
of files
References Ref No
Water 0.33 – 50000 265 – 295 9.99 4 Dowing and Williams (1975),
Kou et al. (1993)
Ray (1972); Hale and Querry (1973)
[5]
[12]
[10], [20]
Water-soluble 250 – 50000 293 9.99 1 Volz et al. (1972a, 1972b, 1973);
Shettle and Fenn (1979)
[30, 31, 32]
[23]
Ice 0 – 225700 130 -273 9.99 15 Clapp et al. (1995),
Fenn et al. (1985),
Kou et al. (1993), Warren (1984)
[3]
[8]
[12], [33]
Ice-film 482 – 6962 163 9.99 1 Toon et al. (1994) [28]

Solids(1) – Salts(2)
Component Spectral
coverage (cm-1)
Temperature
range (K)
Concentration
range (%)
Number
of files
References Ref No
Mineral-dust 250 – 40000 293 9.99 1 Volz (1973)
Carlson and Benjamin (1980)
Sokolik et al. (1993)
[32]
[2]
[24]
Quartz 33 – 50000 293 9.99 2 Longtin et al. (1988);
Gray (1963); Drumond (1936);
Spitzer and Kleinman (1961);
Philipp (1985)
[13]
[9],[16]
[25]
[18]
Hematite 33 – 50000 293 9.99 2 Longtin et al. (1988) [13]
Sand 33 – 50000 293 9.99 2 Longtin et al. (1988) [13]
Insoluble 250 – 40000 293 9.99 1 Shettle and Fenn (1979) [23]
Ammonium Sulfate 250 – 50000 293 9.99 1 Toon et al. (1976) [27]
Meteoric dust 250 – 50000 293 9.99 1 Fenn et al. (1985) [8]
Dusts-like 250 – 50000 293 9.99 1 Shettle and Fenn (1979),
Volz (1972a, 1972b)
[23], [30-31]
Salts 0 – 50000 293 9.99 18 Shettle and Fenn (1979),
Volz (1972a), Dorsey (1940);
Eldridge and Palik (1985)
[23],
[30], [4]
[7]

(1) Solids

Mineral dust: 1 file

Quartz; 2 files, i.e.: quartz-E0ray, quartz-Oray

Hematite; 2 files, i.e.: hematite-Eray, hematite-Oray

Sand; 2 files, i.e.: sand-E00ray, sand-Oray

Insoluble: 1 file

Ammonium Sulfate: 1 file

Meteoric dust:1 file

Dust-like: 1 file

(2) Salts

Sea-salt: 1 file

Sea-salt-coarse: 8 files corresponding respectively to relative humidity 0.0, 0.50, 0.70, 0.80, 0.90, 0.95, 0.98

Sea-salt-accumulation: 8 files corresponding to the same selection of relative humidity as for sea-salt-coarse

Sodium-chloride: 1 file